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Article
Effect of Ca2+ Substitution on the Structure, Microstructure, and Microwave Dielectric Properties of Sr2Al2SiO7 Ceramic
Journal of the American Ceramic Society
  • Kurusaroor Mana Manu, National Institute for Interdisciplinary Science and Technology
  • Chinnathambi Karthik, Boise State University
  • Rick Ubic, Boise State University
  • Mailadil Thomas Sebastian, National Institute for Interdisciplinary Science and Technology
Document Type
Article
Publication Date
12-1-2013
Abstract
The effect of Ca2+ substitution on the structure, microstructure, and microwave dielectric properties of Sr–gehlenite (Sr2Al2SiO7) ceramic has been investigated. The structure and microstructure of Sr2-xCaxAl2SiO7ceramics were analyzed via X-ray diffraction (XRD) as well as scanning and transmission electron microscopic techniques. While the end-members (x = 0 and 2) form isostructural compounds, a highly defective, nonstoichiometric, Ca-rich secondary phase was observed via bright-field transmission electron microscopy and energy dispersive X-ray spectroscopy in compositions corresponding to x = 0.75 and 1.5. The concentration of secondary phase in x = 0.75 is too low to be detected via XRD or scanning electron microscopy. Identical selected-area electron-diffraction patterns of the compounds (x = 0, 1, and 2) confirmed that they belong to the space group P421m (no. 113) with tetragonal crystal symmetry. The porosity-corrected relative permittivity at microwave frequencies showed a gradual increase with Ca2+ content; however, Ca2+ substitution made only marginal changes to the microwave dielectric properties except in the case of x = 1.5, in which the secondary phase reduced the quality factor considerably. Thermal conductivity decreased with increasing Ca2+ content, and the compounds with defective structures showed the lowest thermal conductivity. All the compounds exhibited low coefficients of linear thermal expansion, with values varying in the range 2.3–3.6 ppm/°C.
Citation Information
Kurusaroor Mana Manu, Chinnathambi Karthik, Rick Ubic and Mailadil Thomas Sebastian. "Effect of Ca2+ Substitution on the Structure, Microstructure, and Microwave Dielectric Properties of Sr2Al2SiO7 Ceramic" Journal of the American Ceramic Society (2013)
Available at: http://works.bepress.com/rick_ubic/75/