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Article
Transmission Electron Microscopic Study of Pyrochlore to Defect-Fluorite Transition in Rare-Earth Pyrohafnates
Journal of Solid State Chemistry
  • Chinnathambi Karthik, Boise State University
  • Thomas Anderson, Boise State University
  • Delphine Gout, Oak Ridge National Laboratory
  • Rick Ubic, Boise State University
Document Type
Article
Publication Date
10-1-2012
Abstract
A structural transition in rare earth pyrohafnates, Ln2Hf2O7 (Ln=Y, La, Pr, Nd, Tb, Dy, Yb and Lu), has been identified. Neutron diffraction showed that the structure transforms from well-ordered pyrochloric to fully fluoritic through the lanthanide series from La to Lu with a corresponding increase in the position parameter x of the 48f (Fdm) oxygen site from 0.330 to 0.375. As evidenced by the selected area electron diffraction, La2Hf2O7, Pr2Hf2O7 and Nd2Hf2O7 exhibited a well-ordered pyrocholoric structure with the presence of intense superlattice spots, which became weak and diffuse (in Dy2Hf2O7 and Tb2Hf2O7) before disappearing completely as the series progressed towards the Lu end. High resolution electron microscopic studies showed the breakdown of the pyrochlore ordering in the form of antiphase domains resulting in diffused smoke-like superlattice spots in the case of Dy2Hf2O7 and Tb2Hf2O7.
Citation Information
Chinnathambi Karthik, Thomas Anderson, Delphine Gout and Rick Ubic. "Transmission Electron Microscopic Study of Pyrochlore to Defect-Fluorite Transition in Rare-Earth Pyrohafnates" Journal of Solid State Chemistry (2012)
Available at: http://works.bepress.com/rick_ubic/63/