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Pressure Dissociation of Solid Nitrogen under 1 Mbar
Physical Review Letters (1985)
  • A. K. McMahan, Los Alamos National Laboratory
  • Richard Alan Lesar, Los Alamos National Laboratory
The zero-temperature transition pressure from molecular to monatomic nitrogen is predicted to be less than about 1 Mbar, and should be observable in diamond-anvil cells. This estimate is obtained from total-energy calculations in which compressed molecular nitrogen is found to dissociate into a simple cubic monatomic structure, slight distortions of which are common to other group-V elements. The calculated 35% volume change raises the possibility of a large barrier to dissociation and extensive regions of metastability.
Publication Date
April 29, 1985
Citation Information
A. K. McMahan and Richard Alan Lesar. "Pressure Dissociation of Solid Nitrogen under 1 Mbar" Physical Review Letters Vol. 54 Iss. 17 (1985)
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