"Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization" by Richard H. Perry

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Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization

Angewandte Chemie International Edition

Richard H. Perry, Stanford University
Maurizio Splendore, Stanford University
Allis Chien, Stanford University
Nick K. Davis, Stanford University
Richard N. Zare, Stanford University

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Document Type

Article

Publication Date

1-3-2011

Keywords

Mass spectrometry,
Organometallic catalysis,
Reaction intermediates,
Ruthenium,
Transfer hydrogenation

Disciplines

Abstract

Capturing transient species: The bombardment of a surface‐bound RuII complex with charged droplets containing a ligand allows the detection of reaction intermediates (see figure). The reaction investigated is used to synthesize RuII catalysts containing amino alcohol ligands, which facilitate the asymmetric transfer hydrogenation of ketones and imines.

Comments

Additional Comments

Air Force Office of Scientific Research grant #: FA 9550‐10‐1‐0235

DOI

10.1002/anie.201004861

Citation Information

Richard H. Perry, Maurizio Splendore, Allis Chien, Nick K. Davis, et al.. "Detecting Reaction Intermediates in Liquids on the Millisecond Time Scale Using Desorption Electrospray Ionization" Angewandte Chemie International Edition Vol. 50 Iss. 1 (2011) p. 250 - 254 ISSN: 1433-7851
Available at: http://works.bepress.com/richard-perry/17/