An ore microscopic study of the Boss-Bixby, Missouri, copper-iron deposit has shown that the mineralization formed as a simple sequence of oxides followed by cobaltian sulfides, copper-iron sulfides, and then oxides. The hypogene ore minerals are magnetite, hematite, ilmenite, rutile, chalcopyrite, bornite, covellite, cobaltian pyrite, carrollite, sphalerite, clausthalite, galena, electrum, scheelite, wolframite, and a Pb-Bi-Se-Te mineral. Textural evidence indicates that some of the early oxides were original constituents of the host syenites and oxidized during cooling. The remainder of the mineralization formed as breccia fillings and replacements. Subsequent partial oxidation formed martite, covellite, rutile, and anatase.