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Thermal Stability of Glasses from the Fe₄(P₂O₇)₃-Fe(PO₃)₃ System
Journal of Non-Crystalline Solids
  • Liying Zhang
  • Luciana Ghussn
  • Melodie L. Schmitt
  • Edgar D. Zanotto
  • Richard K. Brow, Missouri University of Science and Technology
  • Mark E. Schlesinger, Missouri University of Science and Technology
Abstract

Iron phosphate glasses with nominal Fe/P compositions between 0.50 and 0.67 were prepared and characterized. The effects of melt conditions and the initial composition on the Fe(II)-content are reported. Characteristic temperatures, including the glass transition temperature and crystallization temperature, were measured by DSC. The stability of melts against crystallization, described by the Angel and Weinberg parameters, generally decreases with increasing O/P and Fe/P ratios. © 2010 Elsevier B.V. All rights reserved.

Department(s)
Materials Science and Engineering
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2010 Elsevier, All rights reserved.
Publication Date
1-1-2010
Publication Date
01 Jan 2010
Citation Information
Liying Zhang, Luciana Ghussn, Melodie L. Schmitt, Edgar D. Zanotto, et al.. "Thermal Stability of Glasses from the Fe₄(P₂O₇)₃-Fe(PO₃)₃ System" Journal of Non-Crystalline Solids (2010) ISSN: 0022-3093; 1873-4812
Available at: http://works.bepress.com/richard-brow/160/