Electrochemical Characterization of Electronically Conductive Polypyrrole on Cyclic VoltammogramsJournal of the Electrochemical Society
Subject Area(s)Chemical Engineering
AbstractExperimental and theoretical cyclic voltammograms for electronically conducting polypyrrole film are obtained from the identical conditions and compared to each other to characterize electrochemical behavior of the polymer. A comparison of the simulated and experimental cyclic yoltammograms shows quantitative agreement. The profiles of the dependent variables show that the switching process is governed by the availability of the counter ion to the polypyrrole electrode and the amount of electroactive sites. Sensitivity analysis shows that the double layer effects have more influence in the cyclic voltammograms than the electrokinetic effects.
Citation InformationTaewhan Yeu, Ken-Ming Yin, Jose Carbajal and Ralph E White. "Electrochemical Characterization of Electronically Conductive Polypyrrole on Cyclic Voltammograms" Journal of the Electrochemical Society (1991) p. 2869 - 2877
Available at: http://works.bepress.com/ralph_white/169/