This study will investigate measuring the wettability contact angles of native unconventional tight carbonate as well as other unconventional pore system reservoir samples that hosts varied pore shapes and subsequent wettability contact angle distributions in both reservoir matrix and possible natural fractures. Also, the investigation will include validation of the grain/ pore-wall wettability regions and classify the natural wettability preference available inside pores of the rock and their overall wettability performance and recovery efficiency contributions. Further investigation will include modeling pore throat contact angle wettability, and to understand their new physics that will advance reservoir characterization and oil recovery improvement.