Article
Origin of the Stabilization of Vinyldiazonium Ions by β-Substitution; First Crystal Structure of an Aliphatic Diazonium Ion: β,β-Diethoxyethene-diazonium Hexachloroantimonate
Angewandte Chemie (International Edition in English)
Abstract
The considerable contributions of the O-stabilized mesomeric resonance structures III and IV probably account for the extraordinary stability of the cation of the title compound and related systems. This is apparent from comparisons of the bond lengths and angles of the first experimentally determined structure with the results of ab initio studies. The title compound is prepared by alkylation of diazoacetate with triethyloxonium hexachloroantimonate.
Department(s)
Chemistry
Sponsor(s)
Petroleum Research Fund of the American Chemical SocietyResearch Council of the University of Missouri
Comments
This research was supported by the Petroleum Research Fund of the American Chemical Society and the Research Council of the University of Missouri (92-RC-023-BR)
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1992 Wiley-VCH Verlag, All rights reserved.
Publication Date
6-1-1992
Publication Date
01 Jun 1992
Disciplines
Citation Information
Rainer Glaser, Grace Shiahuy Chen and Charles Leslie Barnes. "Origin of the Stabilization of Vinyldiazonium Ions by β-Substitution; First Crystal Structure of an Aliphatic Diazonium Ion: β,β-Diethoxyethene-diazonium Hexachloroantimonate" Angewandte Chemie (International Edition in English) Vol. 31 Iss. 6 (1992) p. 740 - 743 ISSN: 0570-0833 Available at: http://works.bepress.com/rainer-glaser/95/