Article
A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement
Journal of the Chemical Society, Chemical Communications
Abstract
Copper(I) oxide reacts with selenol 2,4,6-Pri3C6H2-SeH in ethanol to give the hexanuclear copper(I) selenolate {Cu[Se(2,4,6-Pri3C6H2)]}6 of 6, the solid state structure of which consists of a disordered Cu6 octahedron embedded in an antiprism formed by six selenium centres of the selenolate residues; this leads us to propose an exchange mechanism for the equilibration of all copper positions.
Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1995 Royal Society of Chemistry, All rights reserved.
Publication Date
1-1-1995
Publication Date
01 Jan 1995
Disciplines
Citation Information
Dietmar Ohlmann, Hans Pritzkow, Hansjorg Grutzmacher, Mitchell Anthamatten, et al.. "A Hexanuclear Copper Arylselenolate: Synthesis, Structure and Proposal for Its Rearrangement" Journal of the Chemical Society, Chemical Communications Iss. 10 (1995) p. 1011 - 1012 ISSN: 0022-4936 Available at: http://works.bepress.com/rainer-glaser/22/