Article
β,β-dichlorovinyldiazonium or Dichloro(diazomethyl)carbenium Ion? Crystal Structure and Electron Density Distribution of β,β- Dichlorovinyldiazonium Hexachloroantimonate
Journal of the Chemical Society, Chemical Communications
Abstract
The crystal structure of β,β-dichlorovinyldiazonium hexachloroantimonate, 2·SbCl6, and the topological electron density analysis of 2 provide compelling evidence for the importance of chlorine-stabilized carbenium ion resonance forms for the stabilization of vinyldiazonium ions by β-substitution.
Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1993 Royal Society of Chemistry, All rights reserved.
Publication Date
1-1-1993
Publication Date
01 Jan 1993
Disciplines
Citation Information
Grace Shiahuy Chen, Rainer Glaser and Charles Leslie Barnes. "β,β-dichlorovinyldiazonium or Dichloro(diazomethyl)carbenium Ion? Crystal Structure and Electron Density Distribution of β,β- Dichlorovinyldiazonium Hexachloroantimonate" Journal of the Chemical Society, Chemical Communications Iss. 19 (1993) p. 1530 - 1532 ISSN: 0022-4936 Available at: http://works.bepress.com/rainer-glaser/148/