Article
Polymorphism and C=N-N=C Conformational Isomers of Azines: X-ray Crystal and Ab Initio Structures of Two Rotational Isomers of Methyl (para-Tolyl) Ketone Azine
Angewandte Chemie (International Edition in English)
Abstract
Conjugative effects are not significant for the conformation of diaryl-substituted azines such as 1 - whether within the azine unit or between the aryl substituents and the azine or imino units. This was the conclusion of studies of X-ray crystal structures and quantum chemical calculations.
Department(s)
Chemistry
Sponsor(s)
Petroleum Research Fund of the American Chemical SocietyResearch Board of the University of Missouri
National Science Foundation
Comments
This research was supported by the Petroleum Research Fund of the American Chemical Society, the Research Board of the University of Missouri, and the National Science Foundation, and is part of the projected Ph.D. dissertation of G. S. Chen.
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1994 Wiley-VCH Verlag, All rights reserved.
Publication Date
6-1-1994
Publication Date
01 Jun 1994
Disciplines
Citation Information
Grace Shiahuy Chen, Mitchell Anthamatten, Charles Leslie Barnes and Rainer Glaser. "Polymorphism and C=N-N=C Conformational Isomers of Azines: X-ray Crystal and Ab Initio Structures of Two Rotational Isomers of Methyl (para-Tolyl) Ketone Azine" Angewandte Chemie (International Edition in English) Vol. 33 Iss. 10 (1994) p. 1081 - 1084 ISSN: 0570-0833 Available at: http://works.bepress.com/rainer-glaser/105/