Regioselective synthesis of novel e-edge-fullerenylmethanodihydropyrroles and 1,2-dihydromethanofullerenesFaculty of Science - Papers (Archive)
AbstractTreatment of a tethered N-(diphenylmethylene)glycinate-malonate derivative with fullerene under Bingel conditions yielded an e-edge-fullerenylmethanodihydropyrrole adduct in a regioselective manner. The regiochemical outcome was independent of the order of addition of either the N-(diphenylmethylene)glycinate or the malonate moieties. This new bis-adduct was also prepared in 13C enriched form allowing for its unequivocal structural characterization by 2D INADEQUATE NMR experiments. Ring-opening of the dihydropyrrole functionality of the bisadducts under reductive conditions gave exclusively novel dihydromethanofullerene derivatives.
Citation InformationLeila Chaker, Graham E Ball, James R Williams, Glenn A Burley, et al.. "Regioselective synthesis of novel e-edge-fullerenylmethanodihydropyrroles and 1,2-dihydromethanofullerenes" (2005)
Available at: http://works.bepress.com/pkeller/12/