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Article
Theory of the Seebeck Coefficient in LaCrO₃ and Related Perovskite Systems
Physical Review B (Condensed Matter)
  • D. B. Marsh
  • Paul Ernest Parris, Missouri University of Science and Technology
Abstract

We consider the Seebeck coefficient in LaCrO3 and related transition-metal-oxide perovskites using a model for electronic conduction based on the electronic structure of the 3d orbitals of the B-site transition-metal cations. Relations for the Seebeck coefficient are presented for those perovskite systems in which electronic conduction is through the t2g states of the B-site transition-metal cations. High- and low-temperature limits for the Seebeck coefficient are identified for the cases of both strong and weak magnetic coupling between electron spins. In these high- and low-temperature limits, the Seebeck coefficient is determined as a function of carrier concentration. Results are applied to an analysis of experimental data for the (La,Sr)CrO3

Department(s)
Physics
Document Type
Article - Journal
Document Version
Final Version
File Type
text
Language(s)
English
Rights
© 1996 American Physical Society (APS), All rights reserved.
Publication Date
9-1-1996
Publication Date
01 Sep 1996
Disciplines
Citation Information
D. B. Marsh and Paul Ernest Parris. "Theory of the Seebeck Coefficient in LaCrO₃ and Related Perovskite Systems" Physical Review B (Condensed Matter) Vol. 54 Iss. 11 (1996) p. 7720 - 7728 ISSN: 0163-1829
Available at: http://works.bepress.com/paul-parris/63/