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Surface Chemistry of Perfluoropolyethers and Hydrogenated Analogs: Are Studies of Model Compounds Useful?
Ames Laboratory Conference Papers, Posters, and Presentations
  • M. M. Walczak, Iowa State University
  • Patricia A. Thiel, Iowa State University
Document Type
Book Chapter
Conference
Proceedings of the Third International Workshop on Interface Phenomena
Publication Date
8-1-1989
Geolocation
(44.6488625, -63.5753196)
Abstract
We have studied adsorption, desorption, and decomposition of ethers on Ru(001), an atomically-smooth metal surface. We have compared diethers with monoethers, and fluorinated ethers with hydrogenated ethers. The number of ether linkages does not strongly influence adsorption bond strength, nor the extent of decomposition. Fluorination does weaken the adsorption bond strength and prevents decomposition. These studies suggest that the surface properties of monomeric ethers can be used to predict properties of oligomeric, and perhaps even polymeric, ethers.
Comments

This article is from Adhesion and Friction: Proceedings of the Third International Workshop on Interface Surfaces 17 (1989): pp. 89—97

Copyright Owner
Springer Verlag
Language
en
Citation Information
M. M. Walczak and Patricia A. Thiel. "Surface Chemistry of Perfluoropolyethers and Hydrogenated Analogs: Are Studies of Model Compounds Useful?" Halifax, Nova Scotia(1989)
Available at: http://works.bepress.com/patricia_thiel/98/