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Article
Wetting Kinetics of Polymer Solutions and Force-Based Contact Angles
AIChE Journal
  • Amer Mohammad Al-Shareef
  • Partho Neogi, Missouri University of Science and Technology
  • Baojun Bai, Missouri University of Science and Technology
Abstract

The effect of the shear thinning behavior and elasticity of polymer solutions on the dynamic contact angles are investigated. Under dynamic conditions, the contact angle of a liquid on a solid surface changes significantly with the substrate velocity from its equilibrium value. The dynamic contact angles for polyethylene oxide (PEO) solutions of two molecular weights 3 x 105 and 4 x 106 have been measured using a polyethylene terephthalate (PET) plate. The three-parameter Ellis model to fit the rheological data to obtain shear thinning power n, characteristic shear stress, and the zero-shear viscosity is used. The theory indicates that dynamic contact angles follow power law in this instance instead of showing Newtonian behavior with zero-shear viscosity when the shear thinning effects are considered. The elastic effect becomes important at larger polymer concentrations that reduces the dependence on capillary number, that is, reduces n keeping with the experiments.

Department(s)
Chemical and Biochemical Engineering
Second Department
Geosciences and Geological and Petroleum Engineering
Keywords and Phrases
  • Contact Angle,
  • Non Newtonian Flow,
  • Plastic Bottles,
  • Polyethylene Oxides,
  • Rheology,
  • Rolling Resistance,
  • Shear Stress,
  • Shear Thinning,
  • Shear Viscosity,
  • Surface Chemistry,
  • Wetting,
  • Dynamic Contact Angle,
  • Polyethylene Oxide (PEO),
  • Polyethylene Terephthalates (PET),
  • Polymer Concentrations,
  • Shear Thinning Effect,
  • Shear-Thinning Behavior,
  • Zero Shear Viscosity,
  • Shear Flow,
  • Surface Chemistry/Physics,
  • Transport
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 2016 American Institute of Chemical Engineers (AIChE), All rights reserved.
Publication Date
7-1-2016
Publication Date
01 Jul 2016
Citation Information
Amer Mohammad Al-Shareef, Partho Neogi and Baojun Bai. "Wetting Kinetics of Polymer Solutions and Force-Based Contact Angles" AIChE Journal Vol. 62 Iss. 7 (2016) p. 2533 - 2541 ISSN: 0001-1541; 1547-5905
Available at: http://works.bepress.com/partho-neogi/82/