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Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery
Chemical Physics Letters (2003)
  • Hyung-Tae Kwak
  • Partha Srinivasan, Cleveland State University
  • John R Quine, Florida State University
  • Dominique Massiot
  • Zhehong Gan
Abstract
Satellite transition rotational resonance and magic-angle effects on central-transition spin-echo decay and inversion recovery of half-integer quadrupolar nuclei are presented. Small magic-angle offsets can change the satellite transition rotational resonance condition and consequently lead to dramatic effects on line width, spin-echo decay and inversion recovery. An half degree magic-angle offset lengthens α-Al2O3 spin-echo decay by 50% and inversion-recovery by nearly two orders of magnitude. The theory of satellite transition rotational resonance is presented and the origin of these magic-angle effects is explained.
Keywords
  • Quadrupolar nuclei,
  • STMAS
Disciplines
Publication Date
Summer July 17, 2003
Citation Information
Hyung-Tae Kwak, Partha Srinivasan, John R Quine, Dominique Massiot, et al.. "Satellite transition rotational resonance of homonuclear quadrupolar spins: magic-angle effect on spin-echo decay and inversion recovery" Chemical Physics Letters Vol. 376 Iss. 1-2 (2003) p. 75 - 82
Available at: http://works.bepress.com/partha-srinivasan/5/