Article
Catena-Poly[[(Pyridine-κN)Copper(II)]-μ3-Pyridine-2,6-Dicarboxylato-κ3O2:O2′,N,O6:O6′]
Acta Crystallographica Section E-structure Reports Online
(2009)
Abstract
In the title compound, [Cu(C7H3NO4)(C5H5N)]n, the CuII atom is in a slightly distorted octahedral coordination environment. Each CuII atom is bound to two N atoms and one O atom of the pyridinedicarboxylate (PDA) ligand in a tridentate manner, one N atom of the pyridine molecule and two bridging carboxylate O atoms of adjacent PDA ligands, leading to a linear one-dimensional chain running along the c axis. These chains are further assembled via weak C-H...O and [pi]-[pi] interactions into a three-dimensional supramolecular network structure. The centroid-centroid distance between the [pi]-[pi] interacting pyridine rings is 3.9104 (13) Å. The two N atoms are trans to each other with respect to Cu.
Disciplines
Publication Date
March 15, 2009
DOI
10.1107/S1600536809005212
Publisher Statement
10.1107/S1600536809005212
Citation Information
Manoj Trivedi, Daya Shankar Pandey and Nigam P. Rath. "Catena-Poly[[(Pyridine-κN)Copper(II)]-μ3-Pyridine-2,6-Dicarboxylato-κ3O2:O2′,N,O6:O6′]" Acta Crystallographica Section E-structure Reports Online Vol. 65 Iss. 3 (2009) p. m303 - sup-6 Available at: http://works.bepress.com/nigam-rath/135/
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