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Faculty Selected Works of Nigam Rath
Article
Effect of a Strategically Positioned Methoxy Substituent on the Photochemistry of 3-Aryl-3H-1-Oxacyclopenta[l]Phenanthren-2-Ones
Organic Chemistry International (2010)
  • Roshini K. Thumpakara
  • Binoy Jose
  • Perupparampil A. Unnikrishnan
  • Sreedharan Prathapan
  • Nigam P. Rath
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Abstract
Irradiation of 3-methoxy-3-aryl-3H-1-oxacyclopenta[l]phenanthren-2-one derivatives 5a–d resulted in singlet-mediated decarbonylation reaction leading to the formation of phenanthrene derivatives 9a–d. The structure of the photoproduct was unequivocally established on the basis of X-ray crystallographic analysis.
Disciplines
Publication Date
December 28, 2010
DOI
10.1155/2010/764185
Publisher Statement
10.1155/2010/764185
Citation Information
Roshini K. Thumpakara, Binoy Jose, Perupparampil A. Unnikrishnan, Sreedharan Prathapan, et al.. "Effect of a Strategically Positioned Methoxy Substituent on the Photochemistry of 3-Aryl-3H-1-Oxacyclopenta[l]Phenanthren-2-Ones" Organic Chemistry International Vol. 2010 (2010) p. 1 - 5
Available at: http://works.bepress.com/nigam-rath/128/
Creative Commons license
Creative Commons License
This work is licensed under a Creative Commons CC_BY International License.