Fifteen at-risk new mothers participating in a volunteer home-visiting program were interviewed about their experiences with these home-visitors and their relationships with close family and friends after their babies were born. Results of the qualitative analysis, viewed through the lens of Relational Cultural Theory (RCT), detail the social isolation and personal disconnection that they experienced. Their narratives also provide insights about the volunteers’ use of techniques—such as validation, affirmation, consistency, and emotional and instrumental aid—to enhance the mothers’ self-confidence in caring for their babies, to reduce painful feelings, and to increase interpersonal connections. Recommendations are included for working with couples anticipating a new baby.