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Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex
Journal of the American Chemical Society (2009)
  • Nicholas D Ball, University of Michigan - Ann Arbor
  • Melanie S Sanford, University of Michigan - Ann Arbor
Abstract

This communication describes the rational design and synthesis of the remarkably stable PdIV monoaryl fluoride complex (t-Bu-bpy)PdIV(p-FC6H4)(F)2(FHF) (t-Bu-bpy = 4,4′-di-tert-butyl-2,2′-bipyridine). This and related complexes undergo Ar−F bond formation in the presence of “F+” sources. This work serves as a foundation for the development of PdII/IV-catalyzed coupling reactions to form aryl fluorides.

Disciplines
Publication Date
2009
Citation Information
Nicholas D Ball and Melanie S Sanford. "Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex" Journal of the American Chemical Society Vol. 131 (2009)
Available at: http://works.bepress.com/nicholasdball/6/