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Article
Shaped Optimal Control Pulses for Increased Excitation Bandwidth in EPR
Journal of Magnetic Resonance
  • Philipp E. Spindler
  • Yun Zhang
  • Burkhard Endeward
  • Naum I. Gershenzon, Wright State University - Main Campus
  • Thomas E. Skinner, Wright State University - Main Campus
  • Steffen J. Glaser
  • Thomas F. Prisner
Document Type
Article
Publication Date
5-1-2012
Abstract

A 1 ns resolution pulse shaping unit has been developed for pulsed EPR spectroscopy to enable 14-bit amplitude and phase modulation. Shaped broadband excitation pulses designed using optimal control theory (OCT) have been tested with this device at X-band frequency (9 GHz). FT-EPR experiments on organic radicals in solution have been performed with the new pulses, designed for uniform excitation over a significantly increased bandwidth compared to a classical rectangular π/2 pulse of the same B1 amplitude. The concept of a dead-time compensated prefocused pulse has been introduced to EPR with a self-refocusing of 200 ns after the end of the pulse. Echo-like refocused signals have been recorded and compared to the performance of a classical Hahn-echo sequence. The impulse response function of the microwave setup has been measured and incorporated into the algorithm for designing OCT pulses, resulting in further significant improvements in performance. Experimental limitations and potential new applications of OCT pulses in EPR spectroscopy will be discussed.

DOI
10.1016/j.jmr.2012.02.013
Citation Information
Philipp E. Spindler, Yun Zhang, Burkhard Endeward, Naum I. Gershenzon, et al.. "Shaped Optimal Control Pulses for Increased Excitation Bandwidth in EPR" Journal of Magnetic Resonance Vol. 218 (2012) p. 49 - 58 ISSN: 1090-7807
Available at: http://works.bepress.com/naum_gershenzon/84/