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Polymer Adsorption on Platinum: Surface Coverage Determination Using Iodide-125
Journal of Polymer Science, Part A: Polymer Chemistry
  • Tamir M. Ellis
  • Michael R. Van-De-Mark, Missouri University of Science and Technology
Abstract

In the reported experiments, adsorption of iodide-125, a gamma emitter, was used as a quantitative methodology for polymer adsorption surface coverage analysis. Adsorption of I-125 on clean platinum produced surface elemental ratios of I:Pt of 1:4. the technique was applied to the adsorption of polyethylene glycol terephthalate from trifluoroacetic acid on platinum flags with a 2-cm**2 surface area. This polymer adsorption is approximated by a logarithmic relationship similar to the Temkin isotherm. Polymer coverage attained up to 99. 6% of the surface.

Department(s)
Chemistry
Document Type
Article - Journal
Document Version
Citation
File Type
text
Language(s)
English
Rights
© 1981 Wiley-Blackwell, All rights reserved.
Publication Date
1-1-1981
Publication Date
01 Jan 1981
Disciplines
Citation Information
Tamir M. Ellis and Michael R. Van-De-Mark. "Polymer Adsorption on Platinum: Surface Coverage Determination Using Iodide-125" Journal of Polymer Science, Part A: Polymer Chemistry (1981)
Available at: http://works.bepress.com/michael-van-de-mark/42/