Article
Stabilization of Undercooled Metals via Passivating Oxide Layers
Angewandte Chemie International Edition
Document Type
Article
Disciplines
Publication Version
Accepted Manuscript
Publication Date
2-2-2021
DOI
10.1002/anie.202013489
Abstract
Cool frustration: Engineering composition across a thin surface oxide layer of a metal particle, and stabilizing it with appropriate ligands, leads to a sharp surface stress that frustrates solidification. Chemical potential gradients from compositional variation and ligand inductive effects all contribute to stabilization of a metastable state. An undercooled liquid metal particle is formed, highlighting a new paradigm in engineering energy landscape of a material using thin surface layer, as described by Martin Thuo et al. in their Research Article (DOI: 10.1002/anie.202013489).
Copyright Owner
Wiley‐VCH GmbH
Copyright Date
2021
Language
en
File Format
application/pdf
Citation Information
Andrew Martin, Boyce Chang, Alana M. Pauls, Chuanshen Du, et al.. "Stabilization of Undercooled Metals via Passivating Oxide Layers" Angewandte Chemie International Edition (2021) Available at: http://works.bepress.com/martin_thuo/50/
This is the peer-reviewed version of the following article: Angewandte Chemie International Edition, which has been published in final form at DOI: 10.1002/anie.202013489. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving. Posted with permission.