In this paper, the stationary acceleration of the spherical general helix in a 3-dimensional Lie group is studied by using a bi-invariant metric. The relationship between the Frenet elements of the stationary acceleration curve in 4-dimensional Euclidean space and the intrinsic Frenet elements of the Lie group is outlined. As a consequence, the corresponding curvature and torsion of these curves are computed. In Minkowski space, for the curves on a timelike surface to have a stationary acceleration, a necessary and sufficient condition is refined.