Article
Exploring the Mechanism for the Synthesis of Silsesquioxanes. 4. The Synthesis of T8
Journal of Physical Chemistry A
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
5-1-2005
DOI
10.1021/jp040731b
Abstract
In an attempt to explore the mechanism for the synthesis of silsesquioxanes (POSS), the entire reaction processes from HSi(OH)3 to T8, one of the most common and stable POSS was investigated with electronic structure theory calculations, including electron correlation effects. In addition, the effect of some controlling factors, which play important roles in the reaction mechanism, is discussed.
Copyright Owner
American Chemical Society
Copyright Date
2005
Language
en
File Format
application/pdf
Citation Information
Takako Kudo, Kazuya Machida and Mark S. Gordon. "Exploring the Mechanism for the Synthesis of Silsesquioxanes. 4. The Synthesis of T8" Journal of Physical Chemistry A Vol. 109 Iss. 24 (2005) p. 5424 - 5429 Available at: http://works.bepress.com/mark_gordon/296/
Reprinted (adapted) with permission from Journal of Physical Chemistry A 109 (2005): 5424, doi:10.1021/jp040731b. Copyright 2005 American Chemical Society.