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Article
Particulate Oxalate-to-Sulfate Ratio as an Aqueous Processing Marker: Similarity Across Field Campaigns and Limitations
Physics Faculty Publications
  • Miguel Ricardo A Hilario, University of Arizona
  • Ewan Crosbie, NASA Langley Research Center
  • Paola Angela Bañaga, Ateneo de Manila University
  • Grace Betito, Ateneo de Manila University
  • Rachel A Braun, University of Arizona
  • Maria Obiminda L Cambaliza, Ateneo de Manila University
  • Andrea F Corral, University of Arizona
  • Melliza Templonuevo Cruz, Manila Observatory
  • Jackie E Dibb, University of New Hampshire - Main Campus
  • Genevieve Rose Lorenzo, University of Arizona
  • Alexander B MacDonald, University of Arizona
  • Claire E Robinson, NASA Langley Research Center
  • Michael Shook, NASA Langley Research Center
  • James Bernard Simpas, Ateneo de Manila University
  • Connor Stahl, University of Arizona
  • Edward Winstead, NASA Langley Research Center
  • Luke Ziemba, NASA Langley Research Center
  • Armin Sorooshian, University of Arizona
Document Type
Article
Publication Date
10-11-2021
Disciplines
Abstract

Leveraging aerosol data from multiple airborne and surface-based field campaigns encompassing diverse environmental conditions, we calculate statistics of the oxalate-sulfate mass ratio (median: 0.0217; 95% confidence interval: 0.0154 – 0.0296; R = 0.76; N = 2948). Ground-based measurements of the oxalate-sulfate ratio fall within our 95% confidence interval, suggesting the range is robust within the mixed layer for the submicrometer particle size range. We demonstrate that dust and biomass burning emissions can separately bias this ratio towards higher values by at least one order of magnitude. In the absence of these confounding factors, the 95% confidence interval of the ratio may be used to estimate the relative extent of aqueous processing by comparing inferred oxalate concentrations between air masses, with the assumption that sulfate primarily originates from aqueous processing.

Citation Information
Hilario, M. R., Crosbie, E., Bañaga, P. A., Betito, G., Braun, R. A., Cambaliza, M. O., Corral, A. F., Cruz, M. T., Dibb, J. E., Lorenzo, G. R., MacDonald, A. B., Robinson, C. E., Shook, M., Simpas, J. B., Stahl, C., Winstead, E. L., Ziemba, L. D., & Sorooshian, A. (2021). Particulate oxalate-to-sulfate ratio as an aqueous processing marker: Similarity across field campaigns and limitations. Earth and Space Science Open Archive. https://doi.org/https://doi.org/10.1029/2021GL096520