We consider situations where, in a continuous-time dynamical system, a nonchaotic attractor coexists with a nonattracting chaotic saddle, as in a periodic window. Under the influence of noise, chaos can arise. We investigate the fundamental dynamical mechanism responsible for the transition and obtain a general scaling law for the largest Lyapunov exponent. A striking finding is that the topology of the flow is fundamentally disturbed after the onset of noisy chaos, and we point out that such a disturbance is due to changes in the number of unstable eigendirections along a continuous trajectory under the influence of noise.