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Poly(beta-alanoid-block-beta-alanine)s: Synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly
Chemical Communications
  • Shaohui Lin, The University Of Akron
  • Xinfei Yu, The University Of Akron
  • Yingfeng Tu, The University Of Akron
  • Hongyu Xu
  • Stephen Z. D. Cheng, The University Of Akron
  • Li Jia, The University of Akron
Document Type
Article
Publication Date
5-19-2010
Abstract

The titled diblock copolymers are synthesized via cobalt-catalyzed living carbonylative polymerization of N-alkylaziridines under moderate pressures followed by a deprotection step. The poly(beta-alanine) block is solubilized by the poly(beta-alanoid) block in chloroform and remains fully hydrogen-bonded in the form of a sheet-like assembly.

Citation Information
Shaohui Lin, Xinfei Yu, Yingfeng Tu, Hongyu Xu, et al.. "Poly(beta-alanoid-block-beta-alanine)s: Synthesis via cobalt-catalyzed carbonylative polymerization and self-assembly" Chemical Communications Vol. 46 Iss. 24 (2010) p. 4273 - 4275
Available at: http://works.bepress.com/li_jia/3/