Article
Impact of Linker Engineering on the Catalytic Activity of Metal–Organic Frameworks Containing Pd(II)–Bipyridine Complexes
ACS Catalysis
Document Type
Article
Disciplines
Publication Version
Accepted Manuscript
Publication Date
9-2-2016
DOI
10.1021/acscatal.6b01753
Abstract
A series of mixed-linker bipyridyl metal–organic framework (MOF)-supported palladium(II) catalysts were used to elucidate the electronic and steric effects of linker substitution on the activity of these catalysts in the context of Suzuki–Miyaura cross-coupling reactions. m-6,6′-Me2bpy-MOF-PdCl2 exhibited 110- and 496-fold enhancements in activity compared to nonfunctionalized m-bpy-MOF-PdCl2 and m-4,4′-Me2bpy-MOF-PdCl2, respectively. This result clearly demonstrates that the stereoelectronic properties of metal-binding linker units are critical to the activity of single-site organometallic catalysts in MOFs and highlights the importance of linker engineering in the design and development of efficient MOF catalysts.
Copyright Owner
American Chemical Society
Copyright Date
2016
Language
en
File Format
application/pdf
Citation Information
Xinle Li, Ryan Van Zeeland, Raghu V. Maligal-Ganesh, Yuchen Pei, et al.. "Impact of Linker Engineering on the Catalytic Activity of Metal–Organic Frameworks Containing Pd(II)–Bipyridine Complexes" ACS Catalysis Vol. 6 Iss. 9 (2016) p. 6324 - 6328 Available at: http://works.bepress.com/levi_stanley/23/
This document is the Accepted Manuscript version of a Published Work that appeared in final form as Li, Xinle, Ryan Van Zeeland, Raghu V. Maligal-Ganesh, Yuchen Pei, Gregory Power, Levi Stanley, and Wenyu Huang. "Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd (II)–bipyridine complexes." ACS Catalysis 6, no. 9 (2016): 6324-6328, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see DOI: 10.1021/acscatal.6b01753. Posted with permission.