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Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)
Inorganic Chemistry
  • Steven D. Gray, Iowa State University
  • Joseph Lyndon Thorman, Iowa State University
  • Victor A. Adamian, University of Houston
  • Karl M. Kadish, University of Houston
  • L. Keith Woo, Iowa State University
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
1-1-1998
DOI
10.1021/ic970952e
Abstract

Treatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)TiNPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.

Comments

Reprinted (adapted) with permission from Inorganic Chemistry 37 (1998): 1, doi:10.1021/ic970952e. Copyright 1998 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
Steven D. Gray, Joseph Lyndon Thorman, Victor A. Adamian, Karl M. Kadish, et al.. "Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)" Inorganic Chemistry Vol. 37 Iss. 1 (1998) p. 1 - 4
Available at: http://works.bepress.com/l-woo/60/