Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)Inorganic Chemistry
Publication VersionPublished Version
AbstractTreatment of (TTP)Ti(η2-RC⋮CR) (R = Et or Ph) with PhNNPh results in formation of the azobenzene adduct (TTP)Ti(η2-PhNNPh) (1) in good isolated yield. Complex 1 reacts with (TTP)Ti(η2-RC⋮CR) at elevated temperatures to cleanly afford 2 equiv of the phenylimido compound, (TTP)TiNPh (2). The azobenzene complex, 1, is also formed in low yields by the reaction of the (TTP)TiNPh (2) with excess 1,2-diphenylhydrazine. The electrochemistry of the azobenzene adduct (1) and the phenylimido complex (2) is investigated by cyclic voltammetry experiments.
Copyright OwnerAmerican Chemical Society
Citation InformationSteven D. Gray, Joseph Lyndon Thorman, Victor A. Adamian, Karl M. Kadish, et al.. "Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti(η2-PhNNPh)" Inorganic Chemistry Vol. 37 Iss. 1 (1998) p. 1 - 4
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