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Article
Synthesis and Characterization of Chiral Tetraaza Macrocyclic Nickel(II) and Palladium(II) Complexes
Inorganic Chemistry
  • Guodong Du, Iowa State University
  • Arkady Ellern, Iowa State University
  • L. Keith Woo, Iowa State University
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
1-1-2003
DOI
10.1021/ic025818v
Abstract
Chiral tetraaza macrocyclic nickel(II) and palladium(II) complexes 2a−e, containing one or two (R,R)-(−)-1,2-cyclohexanediyl bridges, were synthesized by template condensation reactions and characterized by 1H and 13C NMR, IR, UV−vis, and mass spectrometry. The electrophilic reactivity of 2a was explored. Crystal structures of Ni complex 2b and metal-free ligand 5were determined by single-crystal X-ray diffraction.
Comments

Reprinted (adapted) with permission from Inorganic Chemistry 42 (2003): 873, doi:10.1021/ic025818v. Copyright 2003 American Chemical Society.

Copyright Owner
American Chemical Society
Language
en
File Format
application/pdf
Citation Information
Guodong Du, Arkady Ellern and L. Keith Woo. "Synthesis and Characterization of Chiral Tetraaza Macrocyclic Nickel(II) and Palladium(II) Complexes" Inorganic Chemistry Vol. 42 Iss. 3 (2003) p. 873 - 877
Available at: http://works.bepress.com/l-woo/114/