Synthesis and Characterization of (lmido)titanium(IV) Porphyrin Complexes. X-ray Structure of (Phenylimido )( tetratolylporphyrinato )titanium(IV)Inorganic Chemistry
Publication VersionPublished Version
AbstractGroup 4 metal complexes containing terminal imido ligands have received considerable attention over the past few years. 2- 7 However, metalloporphyrin species containing imido ligands are quite rare and only a small number have been characterized. 8-11 Smieja et al. recently reported the first X-ray crystallographic study of an organoimido metalloporphyrin complex, (TTP)Os(=NC6~-p-N0z)z. 12· 13 We now wish to report a general method for the preparation of the first (organoimido)titanium porphyrin complexes from the reaction of (TIP)TiCh with lithium amides.
Copyright OwnerAmerican Chemical Society
Citation InformationLisa Mary Berreau, Victor G. Young and L. Keith Woo. "Synthesis and Characterization of (lmido)titanium(IV) Porphyrin Complexes. X-ray Structure of (Phenylimido )( tetratolylporphyrinato )titanium(IV)" Inorganic Chemistry Vol. 34 Iss. 3 (1995) p. 527 - 529
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