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Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex
Organometallics (2009)
  • Kyle A Grice
Abstract

The platinum(II) complex (PN)PtMe2 (1; PN = 2-((di-tert-butylphosphino)methyl)pyridine) reacts with molecular oxygen in benzene or methylene chloride solutions to form (PN)PtMe(OOMe) (2), a platinum(II) methylperoxo complex. The structure of the methylperoxo species 2 was determined by X-ray crystallography.

Disciplines
Publication Date
2009
Citation Information
Kyle A Grice. "Insertion of Dioxygen into a Platinum(II)−Methyl Bond To Form a Platinum(II) Methylperoxo Complex" Organometallics Vol. 28 (2009)
Available at: http://works.bepress.com/kyle_grice/13/