Model for the steady-state growth of porous anodic alumina filmsChemical and Biological Engineering Conference Presentations and Proceedings
Document TypeConference Proceeding
Conference210th ECS Meeting
AbstractSimulations were developed for the distributions of electrical potential and incorporated anions in porous anodic alumina (PAA) films during steady-state growth. Predictions of a model for the potential distribution based on Laplace's equation were compared to those of the current continuity equation in conjunction with high-field conduction. It was found that Laplace's equation, which has been used previously in PAA models, resulted in strong violations of charge conservation, when the current density was evaluated using the high field conduction equation. Interface motion predicted by the current continuity equation was nearly uniform except near convex ridges on the metal-film interface. This model was extended to predict the distribution of anions in the film, since incorporated anions may provide suppression of conduction near the ridge. The spatial distribution of acid anions predicted by the model agreed with experimental observations.
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Copyright OwnerThe Electrochemical Society
Citation InformationJerrod E. Houser and Kurt R. Hebert. "Model for the steady-state growth of porous anodic alumina films" Cancun, Mexico(2006)
Available at: http://works.bepress.com/kurtr_hebert/50/