CdS Quantum Dot-Sensitized Solar Cells Based on Nano-Branched TiO2 ArraysNanoscale Research Letters
SponsorThis work was supported by the National Key Basic Research Program of China (2013CB922303, 2010CB833103), the National Natural Science Foundation of China (60976073, 11274201, 51231007), the 111 Project (B13029), and the National Fund for Fostering Talents of Basic Science (J1103212).
- Solar batteries -- Design and construction,
- Quantum electronics,
- Quantum dots,
- Photovoltaic cells
AbstractNano-branched rutile TiO2 nanorod arrays were grown on F:SnO2 conductive glass (FTO) by a facile, two-step wet chemical synthesis process at low temperature. The length of the nanobranches was tailored by controlling the growth time, after which CdS quantum dots were deposited on the nano-branched TiO2 arrays using the successive ionic layer adsorption and reaction method to make a photoanode for quantum dot-sensitized solar cells (QDSCs). The photovoltaic properties of the CdS-sensitized nano-branched TiO2 solar cells were studied systematically. A short-circuit current intensity of approximately 7 mA/cm2 and a light-to-electricity conversion efficiency of 0.95% were recorded for cells based on optimized nano-branched TiO2 arrays, indicating an increase of 138% compared to those based on unbranched TiO2 nanorod arrays. The improved performance is attributed to a markedly enlarged surface area provided by the nanobranches and better electron conductivity in the one-dimensional, well-aligned TiO2 nanorod trunks
Citation InformationLiu et al.: CdS quantum dot-sensitized solar cells based on nano-branched TiO2 arrays. Nanoscale Research Letters 2014 9:107. doi:10.1186/1556-276X-9-107