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Article
Sediment Cd and Mo Accumulation in the Oxygen-Minimum Zone off Western Baja California Linked to Global Climate Over the Past 52 Kyr
Paleoceanography
  • Walter E Dean, U.S. Geological Survey
  • Yan Zheng, CUNY Queens College
  • Joseph D Ortiz, Kent State University - Kent Campus
  • Alexander van Geen, Columbia University
Publication Date
1-1-2006
Document Type
Article
DOI
10.1029/2005PA001239
Keywords
  • productivity,
  • ventilation,
  • Baja California
Abstract
[1] Concentrations of organic carbon (orgC), cadmium (Cd), and molybdenum (Mo) were measured in two sediment cores raised from depths of 430 and 700 m within the oxygen-minimum zone (OMZ) off southern Baja California at a temporal resolution of ∼0.5 kyr over the past 52 kyr. These records are supplemented with diffuse spectral reflectance (DSR) measurements obtained on board ship soon after collection at a resolution of ∼0.05 kyr. In the core from 700 m depth, a component extracted from the DSR data and the three geochemical proxies generally vary in concert with each other and over a wide range (4–22% orgC; 1–40 mg/kg Cd; 5–120 mg/kg Mo). Intervals of increased orgC, Cd, and Mo accumulation generally correspond to warm periods recorded in the oxygen-isotopic composition of Greenland ice, with the exception of the Bolling/Allerod which is only weakly expressed off Baja California. Concentrations of the biogenic proxies are higher in the core from 430 m depth, but erratic sediment accumulation before 15 ka precludes dating of the older intervals that are laminated and contain elevated orgC, Cd, and Mo concentrations. The new data provide further evidence of an intimate teleconnection between global climate and the intensity of the OMZ and/or productivity along the western margin of North America. On the basis of a comparison with Cd and Mo records collected elsewhere in the region, we conclude that productivity may actually have varied off southern Baja California by no more than a factor of 2 over the past 52 kyr.
Comments

An edited version of this paper was published by AGU. Copyright 2006 American Geophysical Union.

Citation Information
Walter E Dean, Yan Zheng, Joseph D Ortiz and Alexander van Geen. "Sediment Cd and Mo Accumulation in the Oxygen-Minimum Zone off Western Baja California Linked to Global Climate Over the Past 52 Kyr" Paleoceanography Vol. 21 Iss. 4 (2006)
Available at: http://works.bepress.com/joseph_ortiz/8/