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Article
Half-Cycle Pulse Acting on a One-Dimensional Rydberg Atom: Semiclassical Transition Amplitudes in Action and Angle Variables
Physical Review A
  • C. D. Schwieters, William & Mary
  • John B. Delos, William & Mary
Document Type
Article
Department/Program
Physics
Pub Date
2-1-1995
Publisher
American Physical Society
Abstract

In this paper we derive the expression for the transition coefficient used in the preceding paper [C. D. Schwieters and J. B. Delos, Phys. Rev. A 51, 1023 (1995)] for principal-quantum-number transitions in one-dimensional hydrogen caused by half-cycle pulses. We briefly review the methods of Miller [Adv. Chem. Phys. 25, 69 (1974)] and Marcus [Chem. Phys. Lett. 7, 525 (1970); J. Chem. Phys. 54, 3965 (1971)], and then derive the result using the methods of Maslov and Fedoriuk [Semi-Classical Approximation in Quantum Mechanics, (Reidel, Dordrecht, 1981)]. Also, we examine the approximate reduction of hydrogen from three to one dimension and we find a hitherto unknown correction due to the residual motion of one of the ignored degrees of freedom. We discuss the regime of validity of this one-dimensional approximation.

DOI
https://doi.org/10.1103/PhysRevA.51.1030
Disciplines
Citation Information
C. D. Schwieters and John B. Delos. "Half-Cycle Pulse Acting on a One-Dimensional Rydberg Atom: Semiclassical Transition Amplitudes in Action and Angle Variables" Physical Review A Vol. 51 Iss. 2 (1995) p. 1030 - 1041
Available at: http://works.bepress.com/john-delos/44/