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Activated carbon-alginate beads impregnated with surfactant as sustainable adsorbent for efficient removal of methylene blue
International Journal of Biological Macromolecules
  • Noor Ul Alamin, University of Science and Technology, Bannu
  • Amir Sada Khan, University of Science and Technology, Bannu
  • Asma Nasrullah, University of Peshawar
  • Jibran Iqbal, Zayed University
  • Zahoor Ullah, University of Science and Technology, Bannu
  • Israf Ud Din, Prince Sattam Bin Abdulaziz University
  • Nawshad Muhammad, Khyber Medical University Peshawar
  • Shahan Zeb Khan, University of Science and Technology, Bannu
Document Type
Article
Publication Date
4-15-2021
Abstract

A cost-effective and sustainable Calligonum polygonoides biomass based activated carbon (AC) was synthesized. The prepared AC was utilized in the fabrication of carbon-alginate beads for the adsorption of methylene blue (MB) textile dye from aqueous solution. The surface morphology, surface functional groups, elemental analysis and thermal behavior of the prepared beads were investigated using different analytical techniques. Batch adsorption experiments were performed to investigate the adsorption capacity of the beads. Effect of different parameters such as initial pH of MB solution, dose of adsorbent, contact time, initial concentration of MB and temperature were evaluated. The kinetic studies identified pseudo-second order model. Langmuir and Freundlich isotherm models were applied and fitted to the experimental equilibrium data. The beads showed a maximum adsorption capacity of 769 mg/g in basic pH at 30 °C while using 400 mg·L-1 of MB solution. The adsorption process was found to be endothermic and spontaneous as confirmed by the thermodynamic data. The fabricated beads were subjected to recycling which exhibited same adsorption efficiency after six regeneration cycles. The results showed that the AC-alginate beads impregnated with SDS have high adsorption capability and would be used for the efficient removal of cationic dyes from wastewater.

Publisher
Elsevier
Disciplines
Keywords
  • Activated carbon,
  • Adsorption,
  • methylene blue,
  • Alginate,
  • Sodium dodecyl sulphate
Scopus ID

85101199191

Indexed in Scopus
Yes
Open Access
Yes
Open Access Type
Bronze: This publication is openly available on the publisher’s website but without an open license
https://doi.org/10.1016/j.ijbiomac.2021.02.017
Citation Information
Noor Ul Alamin, Amir Sada Khan, Asma Nasrullah, Jibran Iqbal, et al.. "Activated carbon-alginate beads impregnated with surfactant as sustainable adsorbent for efficient removal of methylene blue" International Journal of Biological Macromolecules Vol. 176 (2021) p. 233 - 243 ISSN: <p><a href="https://v2.sherpa.ac.uk/id/publication/issn/0141-8130" target="_blank">0141-8130</a></p>
Available at: http://works.bepress.com/jibran-iqbal/18/