Characterizing Ionic Liquids On the Basis of Multiple Solvation InteractionsJournal of the American Chemical Society
Publication VersionPublished Version
AbstractRoom-temperature ionic liquids (RTILs) are useful in many chemical applications. Recent publications have attempted to determine the polarity of RTILs using empirical solvent polarity scales. The results have indicated that most RTILs have similar polarities. Nevertheless, RTILs are capable of behaving quite differently when used as solvents in organic synthesis, matrixes in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry, liquid−liquid extraction, and as stationary phases in gas chromatography. The work presented in this study uses a linear free energy approach to characterize 17 RTILs on the basis of their distinct multiple solvation interactions with probe solute molecules. This model provides data that can be used to help identify the interactions and properties that are important for specific chemical applications.
Copyright OwnerAmerican Chemical Society
Citation InformationJared L. Anderson, Jie Ding, Thomas Welton and Daniel W. Armstrong. "Characterizing Ionic Liquids On the Basis of Multiple Solvation Interactions" Journal of the American Chemical Society Vol. 124 Iss. 47 (2002) p. 14247 - 14254
Available at: http://works.bepress.com/jared_anderson/19/