![](https://d3ilqtpdwi981i.cloudfront.net/wFlgeLSYsfFj89wAcxqn8jM_aZw=/425x550/smart/https://bepress-attached-resources.s3.amazonaws.com/uploads/41/0e/11/410e1119-1916-4bee-8728-8652bfa318ef/file.jpg)
Article
The Near-infrared Spectrum of NiCl: Analysis of Vibrational Components of System G and System H between 12,500cm^-1 and 13,750^-1
Journal of Molecular Spectroscopy
(2016)
Abstract
The near-infrared spectrum of nickel chloride, NiCl, has been recorded at high resolution from 12,400–12,600 cm−1, 13,200–13,500 cm−1, and 13,600–13,750 cm−1 using intracavity laser absorption spectroscopy, ILS. The NiCl molecules were produced in the plasma discharge of a nickel-lined, copper hollow cathode with ∼1.8 torr of Ar as the sputter gas and a trace amount of CCl4 as the chloride source. Several transitions were observed and analyzed, including the (2, 0), (1, 0), and (0, 1) bands of the [13.0] 2Π3/2–X2Π3/2 transition, System G, and the (1, 0) band of the [12.3] 2Σ−–X2Π3/2 transition, System H. The transitions were analyzed using PGOPHER and obtained molecular parameters are reported. A potential energy curve for the [13.0] 2Π3/2 state has been constructed using the vibrational information from the analyzed transitions.
Disciplines
Publication Date
2016
Citation Information
James O'Brien, Jack C. Harms, Courtney N. Gipson, Ethan M. Grames, et al.. "The Near-infrared Spectrum of NiCl: Analysis of Vibrational Components of System G and System H between 12,500cm^-1 and 13,750^-1" Journal of Molecular Spectroscopy Vol. 321 (2016) p. 78 Available at: http://works.bepress.com/james-obrien/3/