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Article
Irreversible random and cooperative processes on lattices: Spatial correlations
Journal of Mathematical Physics
  • James W. Evans, Iowa State University
  • D. R. Burgess, Iowa State University
  • D. K. Hoffman, Iowa State University
Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
1-1-1984
DOI
10.1063/1.526021
Abstract

For processes where ‘‘filling’’ events occur irreversibly and, in general, cooperatively at the sites of a lattice, the minimal closed hierarchy of rate equations involves only probabilities for (effectively) connected subconfigurations of empty sites. Extended hierarchies of equations for (effectively) disconnected empty subconfigurations couple back to these. Here we consider a solution to the latter via previously developed exact and approximate truncation schemes based on a shielding property of empty sites. Numerical results for several processes are presented for correlation behavior in both autocatalytic and autoinhibitory rate regimes. The asymptotic large separation behavior of the spatial correlations is analyzed most easily by z‐transforming the equations with respect to separations and is fundamentally different from that of equilibrium distributions.

Comments

This article is published as Evans, J. W., D. R. Burgess, and D. K. Hoffman. "Irreversible random and cooperative processes on lattices: Spatial correlations." Journal of mathematical physics 25, no. 10 (1984): 3051-3063, doi:10.1063/1.526021. Posted with permission.

Copyright Owner
American Institute of Physics
Language
en
File Format
application/pdf
Citation Information
James W. Evans, D. R. Burgess and D. K. Hoffman. "Irreversible random and cooperative processes on lattices: Spatial correlations" Journal of Mathematical Physics Vol. 25 Iss. 10 (1984) p. 3051 - 3063
Available at: http://works.bepress.com/james-evans/191/