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Selected Works of Igor I. Slowing
Article
{Mo24Fe12} Macrocycles: Anion Templation with Large Polyoxometalate Guests
Angewandte Chemie International Edition
  • Xikui Fang, Iowa State University
  • Laura Hansen, Iowa State University
  • Fadi Haso, University of Akron Main Campus
  • Panchao Yin, University of Akron
  • Abhishek Pandey, Iowa State University
  • Larry Engelhardt, Francis Marion University
  • Igor I. Slowing, Iowa State University
  • Tao Li, Argonne National Laboratory
  • Tianbo Liu, University of Akron Main Campus
  • Marshall Luban, Iowa State University
  • D. C. Johnston, Iowa State University
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Document Type
Article
Disciplines
Publication Version
Published Version
Publication Date
9-1-2013
DOI
10.1002/anie.201304887
Abstract
POM and circumstance: Nanometer-sized polyoxometalates (POMs) bring a new direction to anion-templated supramolecular chemistry. The Keggin (left) and Dawson-type (right) polyoxoanions direct the assembly of giant metallomacrocycles through an array of weak hydrogen-bonding interactions. The concerted action of multiple hydrogen bonds keeps the templating guests embedded within the hosts, even in the solution state.
Comments

This article is from Angewandte Chemie International Edition 52 (2013): 10500, doi:10.1002/anie.201304887.

Rights
Works produced by employees of the U.S. Government as part of their official duties are not copyrighted within the U.S. The content of this document is not copyrighted.
Language
en
File Format
application/pdf
Citation Information
Xikui Fang, Laura Hansen, Fadi Haso, Panchao Yin, et al.. "{Mo24Fe12} Macrocycles: Anion Templation with Large Polyoxometalate Guests" Angewandte Chemie International Edition Vol. 52 Iss. 40 (2013) p. 10500 - 10504
Available at: http://works.bepress.com/igor_slowing/18/