Skip to main content
Hydrolysis and interactions of D-cellobiose with polycarboxylic acids
Chemistry & Physics Faculty Publications
  • Ananda S. Amarasekara, Prairie View A & M University
  • Bernard Wiredu, Prairie View A & M University
  • Yen Maroney Lawrence, Prairie View A & M University
Document Type
Publication Date

The hydrolysis of cellulose model compound D-cellobiose was studied with a series of eight common polycarboxylic acids and two monocarboxylic acids in aqueous medium using 0.500 mmol -COOH/L at 170 °C. The maleic acid showed the highest catalytic activity with turnover frequency (TOF) of 29.5 h−1. The interaction of carboxylic acids with D-cellobiose in DMSO‑d6 was studied by determination of the pseudo first-order rate constant kH of anomeric -OH exchange rate in cellobiose using 1H NMR spectroscopy. The maleic, oxalic and citric acids showed infinitely large kH values indicating very strong interactions with D-cellobiose. The next highest interactions were found with phthalic acid (kH = 248.8 Hz). The FT-IR studies showed significant carboxylic acid C=O stretching frequency shifts (ΔνC=O) of 12, 13 and 10 cm−1 for maleic, oxalic and acetic acids respectively in mixtures with D-cellobiose.

Citation Information
Ananda S. Amarasekara, Bernard Wiredu and Yen Maroney Lawrence. "Hydrolysis and interactions of D-cellobiose with polycarboxylic acids" (2019)
Available at: