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Acidic Ionic Liquid Catalyzed One-Pot Conversion of Cellulose to Ethyl Levulinate and Levulinic Acid in Ethanol-Water Solvent System
Chemistry & Physics Faculty Publications
  • Ananda S. Amarasekara, Prairie View A & M University
  • Bernard Wiredu, Prairie View A & M University
Document Type
Article
Publication Date
11-27-2014
Abstract

Cellulose can be converted to a mixture of ethyl levulinate and levulinic acid by heating with a Brönsted acidic ionic liquid catalyst in aqueous ethanol medium in a one-pot operation under mild conditions. The highest ethyl levulinate yield of 19.0 % was obtained for a reaction carried out at 170 °C for 12 h in water-ethanol medium containing 38.5 % water and using 1-(1-propylsulfonic)-3-methylimidazolium chloride as the catalyst. The levulinic acid yields continue to increase with increasing water content up to about 54 % water in aqueous ethanol for reactions carried out at 150 °C for 48 h, and the highest levulinic acid yield was 23.7 %. The acidic, ionic liquid catalyst used can be efficiently recovered (96 %) from the water phase with negligible contamination, and the stability of the catalyst was confirmed by comparison of the 1H NMR spectrum of the recovered catalyst with fresh catalyst.

Citation Information
Ananda S. Amarasekara and Bernard Wiredu. "Acidic Ionic Liquid Catalyzed One-Pot Conversion of Cellulose to Ethyl Levulinate and Levulinic Acid in Ethanol-Water Solvent System" (2014)
Available at: http://works.bepress.com/httpswwwpvamuedubcasdepartmentschemistryfaculty-and-staffasamarasekara/18/