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Article
Vanillin-based polymers: IV. Hydrovanilloin epoxy resins
Chemistry & Physics Faculty Publications
  • Ananda S. Amarasekara, Prairie View A & M University
  • Rocio Garcia-Obergon, Prairie View A & M University
  • Audie K. Thompson, Prairie View A & M University
Document Type
Article
Publication Date
1-20-2019
Abstract

In this study, hydrovanilloin synthesized by electrochemical dimerization of vanillin has been used as a renewable substitute for bisphenol A for the preparation of epoxy resins. The reaction of the disodium salt of hydrovanilloin:epichlorohydrin 1:2 mol ratio at 80°C for 30 min in water gave a hydrovanilloin – diglycidyl ether phenoxy resin. This hard thermoplastic resin showed Tg of 135°C and stable up to 255°C in air. On the other hand, the disodium salt of hydrovanilloin:epichlorohydrin 1:4 mol ratio at 80°C for 30 min in water gives a curable oligomer of hydrovanilloin – diglycidyl ether with 2.1 repeating units. This oligomer could be cured with aliphatic diamines: 1,2-diaminoethane, 1,4-diaminobutane, 1,6-diaminohexane, and isophorone diamine to give hard epoxy resins with Tg values of 116, 118, 149 and 146°C, respectively. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47000.

Citation Information
Ananda S. Amarasekara, Rocio Garcia-Obergon and Audie K. Thompson. "Vanillin-based polymers: IV. Hydrovanilloin epoxy resins" (2019)
Available at: http://works.bepress.com/httpswwwpvamuedubcasdepartmentschemistryfaculty-and-staffasamarasekara/101/