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Synthesis and Spectroscopic Characterization of organotin(IV) Complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of PhSnCl2(BPCT)
Inorganica Chimica Acta (2011)
  • Hapipah Mohd Ali, University of Malaya
  • Affan M. A.
  • Salam M. A.
  • Ahmad F. B.
  • Ismail J.
  • Shamsuddin M. B.
Abstract

The reaction of 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone [HBPCT, (1)] ligand with organotin(IV) chloride(s) lead to the formation of three new organotin(IV) complexes: [MeSnCl2(BPCT)] (2), [PhSnCl2(BPCT)] (3) and [Ph2SnCl(BPCT)] (4). The ligand (1) and its organotin(IV) complexes (2-4) have been synthesized and characterized by CHN analyses, molar conductivity, UV-Vis, FT-IR and H-1 NMR spectral studies. The single crystal X-ray diffraction studies indicated that [PhSnCl2(BPCT)] (3) is six coordinated and adopts strongly a distorted octahedral configuration with the coordination through pyridine-N, azomethine-N and thiolato-S atoms of the ligand. The crystal system of [PhSnCl2(BPCT)] (3) is orthorhombic with space group P2ac2n and the unit cell dimensions: a = 28.1363(5) angstrom, b = 9.5970(2) angstrom, c = 9.4353(2) angstrom.

Publication Date
2011
Citation Information
Hapipah Mohd Ali, Affan M. A., Salam M. A., Ahmad F. B., et al.. "Synthesis and Spectroscopic Characterization of organotin(IV) Complexes with 2-benzoylpyridine-N(4)-cyclohexylthiosemicarbazone (HBPCT): X-ray crystal structure of PhSnCl2(BPCT)" Inorganica Chimica Acta Vol. 366 Iss. 1 (2011)
Available at: http://works.bepress.com/hapipah_mohdali/3/