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Article
One-pot non-template synthesis of hierarchical ZSM-5 from kaolin source
Solid State Sciences (2019)
  • Djoko Hartanto, Institut Teknologi Sepuluh Nopember
  • Riskaviana Kurniawati, Institut Teknologi Sepuluh Nopember
  • Agung Bagus Pambudi, Institut Teknologi Sepuluh Nopember
  • Wahyu Prasetyo Utomo, Institut Teknologi Sepuluh Nopember
  • Wai Loon Leaw, University Technology Malaysia
  • Hadi Nur, University Technology Malaysia
Abstract
Hierarchical ZSM-5 was synthesized without organic template and seed-assisted from the abundant natural source, kaolin, via the facile 1-step hydrothermal process. The hierarchical structure was able to be well-controlled solely on the Na2O/Al2O3 ratio of the precursor. This method is not only simple but greener from the scientific point of view. As revealed, kaolin layered structure that dispersed in the highly alkaline NaOH medium prompts the formation of zeolite as the molecular organization is induced. The excess of NaOH acts as desilication agent after the formation of zeolite as proven by the 29Si MAS NMR data.
Keywords
  • Hierarchical ZSM-5,
  • Kaolin-based ZSM-5,
  • Hydrothermal synthesis of ZSM-5
Publication Date
Winter January 2, 2019
DOI
10.1016/j.solidstatesciences.2018.11.015
Citation Information
Djoko Hartanto, Riskaviana Kurniawati, Agung Bagus Pambudi, Wahyu Prasetyo Utomo, et al.. "One-pot non-template synthesis of hierarchical ZSM-5 from kaolin source" Solid State Sciences Vol. 87 (2019) p. 150 - 154
Available at: http://works.bepress.com/hadi_nur/150/