Use of ionic liquids for pi-conjugated polymer electochemical devicesFaculty of Engineering - Papers (Archive)
AbstractPi-Conjugated polymers that are electrochemically cycled in ionic liquids have enhanced lifetimes without failure (up to 1 million cycles) and fast cycle switching speeds (100 ms). We report results for electrochemical mechanical actuators, electrochromic windows, and numeric displays made from three types of -conjugated polymers: polyaniline, polypyrrole, and polythiophene. Experiments were performed under ambient conditions, yet the polymers showed negligible loss in electroactivity. These performance advantages were obtained by using environmentally stable, room-temperature ionic liquids composed of 1-butyl-3-methyl imidazolium cations together with anions such as tetrafluoroborate or hexafluorophosphate.
Citation InformationW. Lu, A. G. Fadeev, B. Qi, E. Smela, et al.. "Use of ionic liquids for pi-conjugated polymer electochemical devices" (2002)
Available at: http://works.bepress.com/gwallace/13/