
Article
Chemoselective Samarium-Mediated Benzoyloxysulfone Eliminations
The Journal of Organic Chemistry
(2011)
Abstract
An investigation of the substrate dependence on the rate of samarium-mediated reductive elimination of β-acyloxysulfones has provided insights into the mechanism of this transformation and allowed for the development of a chemoselective elimination process.
Keywords
- Chemoselective eliminations,
- Samarium-mediated reductive elimination
Disciplines
Publication Date
2011
DOI
10.1021/jo201734t
Publisher Statement
Copyright © 2011 American Chemical Society
Citation Information
Gregory W. O'Neil and Erasmus O. Volz. "Chemoselective Samarium-Mediated Benzoyloxysulfone Eliminations" The Journal of Organic Chemistry Vol. 76 Iss. 20 (2011) p. 8428 - 8432 Available at: http://works.bepress.com/gregory_oneil/12/